Bis(ethylenediamine-κ2 N,N′)(nitrato-κ2 O,O′)cobalt(III) hydroxide nitrate
نویسندگان
چکیده
The Co ion in the title salt, [Co(NO(3))(H(2)NCH(2)CH(2)NH(2))(2)](OH)(NO(3)), has oxidation state + III and is coordinated by four N atoms from two ethyl-enediamine mol-ecules and two O atoms from a nitrate anion in a distorted octa-hedral geometry. The charge of the complex cation is balanced by a hydroxide anion and a nitrate anion. The cations and anions are connected by N-H⋯O and O-H⋯O hydrogen bonds, resulting in a three-dimensional supra-molecular framework. There are two independent ion pairs with similar configurations in the unit cell. Both uncoordinated nitrate counter-anions are disordered.
منابع مشابه
Reinvestigation of bis(2,2′-bipyridine)(nitrato-κ2 O,O′)cobalt(III) hydroxide nitrate tetrahydrate. Corrigendum
The chemical formula in the paper by Wojciechowska & Daszkiewicz [Acta Cryst. (2007), E63, m2975-m2976] is corrected.[This corrects the article on p. m2975 in vol. 63.].
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009